1869, originally in chemistry, "having more than one degree of valency," from multi- "many" + -valent (see valence in the chemistry sense). Related Multivalence.
Entries linking to multivalent
multi-
before vowels mult-, word-forming element meaning "many, many times, much," from combining form of Latin multus "much, many," from PIE *ml-to-, from root *mel- (2) "strong, great, numerous." It was much-used in forming Latin compounds in classical times and after (such as multianimis "having much courage," multibibus "much-drinking," multicomus "having much hair," multiloquus "talkative"). Many English words that use it (multinational, etc.) are 20c. coinages.
valence n.
early 15c., "extract, preparation," from Latin valentia "strength, capacity," from valentem (nominative valens) "strong, stout, vigorous, powerful," present participle of valere "be strong" (from PIE root *wal- "to be strong"). Chemistry sense of "relative combining capacity of an element with other atoms when forming compounds or molecules" is recorded from 1884, from German Valenz (1868), from the Latin word. Related: Valency.
*wal-
Proto-Indo-European root meaning "to be strong."
It forms all or part of: ambivalence; Arnold; avail; bivalent; convalesce; countervail; Donald; equivalent; evaluation; Gerald; Harold; invalid (adj.1) "not strong, infirm;" invalid (adj.2) "of no legal force;" Isold; multivalent; polyvalent; prevalent; prevail; Reynold; Ronald; valediction; valence; Valerie; valetudinarian; valiance; valiant; valid; valor; value; Vladimir; Walter; wield.
It is the hypothetical source of/evidence for its existence is provided by: Latin valere "be strong, be well, be worth;" Old Church Slavonic vlasti "to rule over;" Lithuanian valdyti "to have power;" Celtic *walos- "ruler," Old Irish flaith "dominion," Welsh gallu "to be able;" Old English wealdan "to rule," Old High German -walt, -wald "power" (in personal names), Old Norse valdr "ruler."