Latin, literally "out of the books (of)," from ex "out of" (see ex-) + ablative plural of liber "book" (see library). Hence, ex-librist (1880).
Entries linking to ex libris
ex-
word-forming element, in English meaning usually "out of, from," but also "upwards, completely, deprive of, without," and "former;" from Latin ex "out of, from within; from which time, since; according to; in regard to," from PIE *eghs "out" (source also of Gaulish ex-, Old Irish ess-, Old Church Slavonic izu, Russian iz). In some cases also from Greek cognate ex, ek. PIE *eghs had comparative form *eks-tero and superlative *eks-t(e)r-emo-. Often reduced to e- before -b-, -d-, -g-, consonantal -i-, -l-, -m-, -n-, -v- (as in elude, emerge, evaporate, etc.).
library n.
place for books, late 14c., from Anglo-French librarie, Old French librairie, librarie "collection of books; bookseller's shop" (14c.), from Latin librarium "book-case, chest for books," and libraria "a bookseller's shop," in Medieval Latin "a library," noun uses of the neuter and fem., respectively, of librarius "concerning books," from Latin librarium "chest for books," from liber (genitive libri) "book, paper, parchment."
Latin liber (from Proto-Italic *lufro-) was originally "the inner bark of trees," and perhaps is from PIE *lubh-ro- "leaf, rind," a derivative of the PIE root *leub(h)- "to strip, to peel" (see leaf (n.)). Comparing Albanian labë "rind, cork;" Lithuanian luobas "bast," Latvian luobas "peel," Russian lub "bast," de Vaan writes that, "for want of a better alternative, we may surmise that liber is cognate with *lubh- and goes back to a PIE word or a European word 'leaf, rind.'"
The equivalent word in most Romance languages survives only in the sense "bookseller's shop" (French libraire, Italian libraria). Old English had bochord, literally "book hoard." As an adjective, Blount (1656) has librarious.