"eight-sided and eight-angled," 1570s, from octagon + -al (1).
Entries linking to octagonal
octagon n.
in geometry, "a plane figure having eight angles and eight sides," 1650s, from Latin octagonos, from Greek oktagōnos, literally "eight-angled, eight-cornered," from okta- combining form of okto "eight" (see eight) + gōnia "angle," which is related to gony "knee" (from PIE root *genu- (1) "knee; angle"). Also octogon (1650s), from French octogone.
-al 1
suffix forming adjectives from nouns or other adjectives, "of, like, related to, pertaining to," Middle English -al, -el, from French or directly from Latin -alis (see -al (2)).