1834, "of or pertaining to (scientific) observation," from observation + -al (1).
Entries linking to observational
observation n.
late 14c., observacioun, "the performance of a religious rite," from Old French observation (c. 1200) and directly from Latin observationem (nominative observatio) "a watching over, observance, investigation," noun of action from past-participle stem of observare "watch over, note, heed, look to, attend to, guard, regard, comply with," from ob "in front of, before" (see ob-) + servare "to watch, keep safe," from PIE root *ser- (1) "to protect." Sense of "act or fact of paying attention" is from 1550s. Meaning "a remark in reference to something observed" is recorded from 1590s.
-al 1
suffix forming adjectives from nouns or other adjectives, "of, like, related to, pertaining to," Middle English -al, -el, from French or directly from Latin -alis (see -al (2)).