"piece of some chemical composition with which a match is tipped," 1860, from match (n.1) + head (n.).
Entries linking to match-head
match n.1
"stick for striking fire." Late 14c., macche, "wick of a candle or lamp," a sense now obsolete, from Old French meiche "wick of a candle," from Vulgar Latin *micca/*miccia (source also of Catalan metxa, Spanish mecha, Italian miccia), which is of uncertain origin, probably ultimately from Latin myxa, from Greek myxa "lamp wick," originally "mucus," based on notion of wick dangling from the spout of a lamp like snot from a nostril, from PIE root *meug- "slimy, slippery" (see mucus). English snot also had a secondary sense from late 14c. of "snuff of a candle, burnt part of a wick," surviving at least to late 19c. in northern dialects.
The modern spelling is from mid-15c. The meaning "piece of cord or tow soaked in sulfur, used for lighting fires, lamps, candles, etc." is from 1530. It was used by 1830 for the modern type of sulfur-tipped wooden friction match, which were perfected about that time, and competed with lucifer for much of 19c. as the name for this invention. An earlier version consisted of a thin strip of wood tipped with combustible matter that required contact with phosphorous carried separately in a box or vial.
In the manufacture of matches much trouble has been occasioned by the use of phosphorous .... In some of the small and poorly-managed factories the men and children are never free from the fumes; their clothes and breath are luminous in the dark, and in the daytime white fumes may be seen escaping from them whenever they are seated by the fire. ... The danger arising from the use of matches was magnified, because they could sometimes be seen in the dark, were liable to ignite on a warm shelf, and were poisonous to such an extent that children had been killed by using them as playthings. [John A. Garver, "Matches," in The Popular Science Monthly, August 1877]
head n.
Old English heafod "top of the body," also "upper end of a slope," also "chief person, leader, ruler; capital city," from Proto-Germanic *haubid (source also of Old Saxon hobid, Old Norse hofuð, Old Frisian haved, Middle Dutch hovet, Dutch hoofd, Old High German houbit, German Haupt, Gothic haubiþ "head"), from PIE root *kaput- "head."
Modern spelling is early 15c., representing what was then a long vowel (as in heat) and remained after pronunciation shifted. Of rounded tops of plants from late 14c. Meaning "origin of a river" is mid-14c. Meaning "obverse of a coin" (the side with the portrait) is from 1680s; meaning "foam on a mug of beer" is first attested 1540s; meaning "toilet" is from 1748, based on location of crew toilet in the bow (or head) of a ship.
Synechdochic use for "person" (as in head count) is first attested late 13c.; of cattle, etc., in this sense from 1510s. As a height measure of persons, from c. 1300. Meaning "drug addict" (usually in a compound with the preferred drug as the first element) is from 1911.
To be over (one's) head "beyond one's comprehension" is by 1620s. To give head "perform fellatio" is from 1950s. Phrase heads will roll "people will be punished" (1930) translates Adolf Hitler. Head case "eccentric or insane person" is from 1966. Head game "mental manipulation" attested by 1972.