1836, "an expert on cleanliness," from hygiene + -ist. Earlier was hygeist (1716). Dental sense is recorded by 1913.
Entries linking to hygienist
hygiene n.
1670s, from French hygiène, ultimately from Greek hygieine techne "the healthful art," from hygies "healthy, sound, hearty," literally "living well" (personified as the goddess Hygieia), from PIE *eyu-gwie-es- "having a vigorous life," from root *aiw-, *ayu- "vital force, life, long life, eternity; in the prime of life, young" (source of Latin aevus, English ever). The Greek adjective was used by Aristotle as a noun meaning "health." The difficult spelling in English is a relic of the struggle to render the Greek vowels into French.
-ist
word-forming element meaning "one who does or makes," also used to indicate adherence to a certain doctrine or custom, from French -iste and directly from Latin -ista (source also of Spanish, Portuguese, Italian -ista), from Greek agent-noun ending -istes, which is from -is-, ending of the stem of verbs in -izein, + agential suffix -tes.
Variant -ister (as in chorister, barrister) is from Old French -istre, on false analogy of ministre. Variant -ista is from Spanish, popularized in American English 1970s by names of Latin-American revolutionary movements.