1540s, from cool on the model of warmth. It persists, and was used by Pound, Kipling, etc., but it never has shaken its odor of facetiousness and become standard.
Entries linking to coolth
cool adj.
Old English col "not warm" (but usually not as severe as cold), "moderately cold, neither warm nor very cold," also, figuratively, of persons, "unperturbed, undemonstrative, not excited or heated by passions," from Proto-Germanic *koluz (source also of Middle Dutch coel, Dutch koel, Old High German chuoli, German kühl "cool," Old Norse kala "be cold"), from PIE root *gel- "cold; to freeze."
Attested in a figurative sense from early 14c. as "manifesting coldness, apathy, or dislike." Applied since 1728 to large sums of money to give emphasis to amount. Meaning "calmly audacious" is from 1825.
Slang use of cool for "fashionable" is by 1933, originally African-American vernacular; its modern use as a general term of approval is from the late 1940s, probably via bop talk and originally in reference to a style of jazz; the word is said to have been popularized in jazz circles by tenor saxophonist Lester Young (1909-1959). Cool-headed "not easily excited or confused" is from 1742.
warmth n.
late 12c., wearmth, Proto-Germanic *warmitho- (source also of Middle Low German wermede, Dutch warmte), from *warmo- (see warm (adj.); also see -th (2)).