1827, "to put into flames," from Vulcan (q.v.), name of the Roman god of fire, + -ize. As a treatment for rubber, attested by 1846. Related: Vulcanized; vulcanizing.
Entries linking to vulcanize
Vulcan n.
god of fire and metal-work in Roman mythology, 1510s, from Latin Vulcanus, Volcanus, according to Klein a word of Etruscan origin. Often with allusions to his lameness and the unfaithfulness of his wife, Venus. As the name of a hypothetical planet between Mercury and the Sun, it is attested from 1860 in English (see intramercurial). The Roman feast of Vulcanalia was on Aug. 23.
-ize
word-forming element used to make verbs, Middle English -isen, from Old French -iser/-izer, from Late Latin -izare, from Greek -izein, a verb-forming element denoting the doing of the noun or adjective to which it is attached.
The variation of -ize and -ise began in Old French and Middle English, perhaps aided by a few words (such as surprise, see below) where the ending is French or Latin, not Greek. With the classical revival, English partially reverted to the correct Greek -z- spelling from late 16c. But the 1694 edition of the authoritative French Academy dictionary standardized the spellings as -s-, which influenced English.
In Britain, despite the opposition to it (at least formerly) of OED, Encyclopaedia Britannica, the Times of London, and Fowler, -ise remains dominant. Fowler thinks this is to avoid the difficulty of remembering the short list of common words not from Greek which must be spelled with an -s- (such as advertise, devise, surprise). American English has always favored -ize. The spelling variation involves about 200 English verbs.