late 14c., "idle," from un- (1) "not" + past participle of occupy (v.). In reference to ground, etc., "not possessed, not made use of," from early 15c.
Entries linking to unoccupied
un- 1
prefix of negation, Old English un-, from Proto-Germanic *un- (source also of Old Saxon, Old Frisian, Old High German, German un-, Gothic un-, Dutch on-), from PIE *n- (source of Sanskrit a-, an- "not," Greek a-, an-, Old Irish an-, Latin in-), combining form of PIE root *ne- "not." Often euphemistic (such as untruth for "lie").
The most prolific of English prefixes, freely and widely used in Old English, where it forms more than 1,000 compounds. It underwent a mass extinction in early Middle English, but emerged with renewed vigor 16c. to form compounds with native and imported words. It disputes with Latin-derived cognate in- (1) the right to form the negation of certain words (indigestable/undigestable, etc.), and though both might be deployed in cooperation to indicate shades of meaning (unfamous/infamous), typically they are not.
It also makes words from phrases (such as uncalled-for, c. 1600; undreamed-of, 1630s; uncome-at-able, 1690s; unputdownable, 1947, of a book; un-in-one-breath-utterable, Ben Jonson; etc., but the habit is not restricted to un-; such as put-up-able-with, 1812). As a prefix in telegramese to replace not and save the cost of a word, it is attested by 1936.
occupy v.
mid-14c., occupien, "to take possession of and retain or keep," also "to take up space or room or time; employ (someone)," irregularly borrowed from Old French ocuper, occuper "occupy (a person or place), hold, seize" (13c.) or directly from Latin occupare "take over, seize, take into possession, possess, occupy," from ob "over" (see ob-) + intensive form of capere "to grasp, seize," from PIE root *kap- "to grasp."
The final syllable of the English word is difficult to explain, but it is as old as the record; perhaps it is from a modification made in Anglo-French. During 16c.-17c. the word was a common euphemism for "have sexual intercourse with" (a sense attested from early 15c.), which caused it to fall from polite usage.
"A captaine? Gods light these villaines wil make the word as odious as the word occupy, which was an excellent good worde before it was il sorted." [Doll Tearsheet in "2 Henry IV"]
During the same time occupant could mean "prostitute." Related: Occupied; occupying.