mid-15c., from un- (2) "reverse, opposite of" + learn (v.).
Entries linking to unlearn
un- 2
prefix of reversal, deprivation, or removal (as in unhand, undo, unbutton), Old English on-, un-, from Proto-Germanic *andi- (source also of Old Saxon ant-, Old Norse and-, Dutch ont-, Old High German ant-, German ent-, Gothic and- "against"), from PIE *anti "facing opposite, near, in front of, before, against" (from PIE root *ant- "front, forehead," with derivatives meaning "in front of, before").
More or less confused with un- (1) through similarity in the notions of "negation" and "reversal;" an adjective such as unlocked might represent "not locked" (un- (1)) or the past tense of unlock (un- (2)).
learn v.
Old English leornian "to get knowledge, be cultivated; study, read, think about," from Proto-Germanic *lisnojanan (cognates: Old Frisian lernia, Middle Dutch leeren, Dutch leren, Old High German lernen, German lernen "to learn," Gothic lais "I know"), with a base sense of "to follow or find the track," from PIE root *lois- "furrow, track." It is related to German Gleis "track," and to Old English læst "sole of the foot" (see last (n.1)).
From c. 1200 as "to hear of, ascertain." Transitive use (He learned me (how) to read), now considered vulgar (except in reflexive expressions, I learn English), was acceptable from c. 1200 until early 19c. It is preserved in past-participle adjective learned "having knowledge gained by study." Old English also had læran "to teach" (see lere). Related: Learning.