1690s, from un- (1) "not" + past participle of explore (v.).
Entries linking to unexplored
un- 1
prefix of negation, Old English un-, from Proto-Germanic *un- (source also of Old Saxon, Old Frisian, Old High German, German un-, Gothic un-, Dutch on-), from PIE *n- (source of Sanskrit a-, an- "not," Greek a-, an-, Old Irish an-, Latin in-), combining form of PIE root *ne- "not." Often euphemistic (such as untruth for "lie").
The most prolific of English prefixes, freely and widely used in Old English, where it forms more than 1,000 compounds. It underwent a mass extinction in early Middle English, but emerged with renewed vigor 16c. to form compounds with native and imported words. It disputes with Latin-derived cognate in- (1) the right to form the negation of certain words (indigestable/undigestable, etc.), and though both might be deployed in cooperation to indicate shades of meaning (unfamous/infamous), typically they are not.
It also makes words from phrases (such as uncalled-for, c. 1600; undreamed-of, 1630s; uncome-at-able, 1690s; unputdownable, 1947, of a book; un-in-one-breath-utterable, Ben Jonson; etc., but the habit is not restricted to un-; such as put-up-able-with, 1812). As a prefix in telegramese to replace not and save the cost of a word, it is attested by 1936.
explore v.
1580s, "to investigate, examine," a back-formation from exploration, or else from French explorer (16c.), from Latin explorare "investigate, search out, examine, explore," said to be originally a hunters' term meaning "set up a loud cry," from ex "out" (see ex-) + plorare "to weep, cry." Compare deplore. De Vaan notes modern sources that consider "the ancient explanation, ... that the verb explorare originally meant 'to scout the hunting area for game by means of shouting'" to be "not unlikely." Second element also is explained as "to make to flow," from pluere "to flow." Meaning "to go to a country or place in quest of discoveries" is first attested 1610s. Related: Explored; exploring.