afternoon n.

Old English æfter "behind; later in time" (adv.); "behind in place; later than in time; in pursuit, following with intent to overtake" (prep.), from of "off" (see off (adv.)) + -ter, a comparative suffix; thus the original meaning was "more away, farther off." Compare Old Norse eptir "after," Old Frisian efter, Dutch achter, Old High German aftar, Gothic aftra "behind;" also see aft. Cognate with Greek apotero "farther off," Old Persian apataram "further."

From c. 1300 as "in imitation of." As a conjunction, "subsequent to the time that," from late Old English. After hours "hours after regular working hours" is from 1814. Afterwit "wisdom that comes too late" is attested from c. 1500 but seems to have fallen from use. After you as an expression in yielding precedence is recorded by 1650.

mid-12c., non "midday," in exact use, "12 o'clock p.m.," also "midday meal," from Old English non "3 o'clock p.m., the ninth hour from sunrise," also "the canonical hour of nones," from Latin nona hora "ninth hour" of daylight, by Roman and ecclesiastical reckoning about 3 p.m., from nona, fem. singular of nonus "ninth," contracted from *novenos, from novem "nine" (see nine).

The sense shift from "3 p.m." to "12 p.m." began during 12c., and various reasons are given for it, such as unreliability of medieval time-keeping devices and the seasonal elasticity of the hours of daylight in northern regions. In monasteries and on holy days, fasting ended at nones, which perhaps offered another incentive to nudge it up the clock. Or perhaps the sense shift was based on an advance in the customary time of the (secular) midday meal. Whatever the cause, the meaning change from "ninth hour" to "sixth hour" seems to have been complete by 14c. (the same evolution is in Dutch noen).

From 17c. to 19c., noon sometimes also meant "midnight" (the noon of the night).

"the middle of the afternoon," c. 1400, from mid (adj.) + afternoon. Earlier in the same sense was mid-overnoon (late 13c.).