"on fire, ablaze," 1550s, from a- (1) "on" + flame (n.). Figurative use by 1856.
Entries linking to aflame
a- 1
prefix or inseparable particle, a conglomerate of various Germanic and Latin elements.
In words derived from Old English, it commonly represents Old English an "on, in, into" (see on (prep.)), as in alive, above, asleep, aback, abroad, afoot, ashore, ahead, abed, aside, obsolete arank "in rank and file," etc., forming adjectives and adverbs from nouns, with the notion "in, at; engaged in." In this use it is identical to a (2).
It also can represent Middle English of (prep.) "off, from," as in anew, afresh, akin, abreast. Or it can be a reduced form of the Old English past participle prefix ge-, as in aware.
Or it can be the Old English intensive a-, originally ar- (cognate with German er- and probably implying originally "motion away from"), as in abide, arise, awake, ashamed, marking a verb as momentary, a single event. Such words sometimes were refashioned in early modern English as though the prefix were Latin (accursed, allay, affright are examples).
In words from Romanic languages, often it represents reduced forms of Latin ad "to, toward; for" (see ad-), or ab "from, away, off" (see ab-); both of which by about 7c. had been reduced to a in the ancestor of Old French. In a few cases it represents Latin ex.
[I]t naturally happened that all these a- prefixes were at length confusedly lumped together in idea, and the resultant a- looked upon as vaguely intensive, rhetorical, euphonic, or even archaic, and wholly otiose. [OED]
flame n.
Middle English flaume, also flaumbe, flambe, flame, flamme, mid-14c., "a flame;" late 14c., "a flaming mass, a fire; fire in general, fire as an element;" also figurative, in reference to the "heat" or "fire" of emotions, from Anglo-French flaume, flaumbe "a flame" (Old French flambe, 10c.), from Latin flammula "small flame," diminutive of flamma "flame, blazing fire," from PIE *bhleg- "to shine, flash," from root *bhel- (1) "to shine, flash, burn."
The meaning "a sweetheart, object of one's passion" is attested from 1640s; the figurative sense of "burning passion" was in Middle English, and the nouns in Old French and Latin also meant "fire of love, flame of passion," and, in Latin "beloved object." The Australian flame-tree is from 1857, so called for its red flowers.